User is not able to set Min, Max occurs values in Data Element or Types tab.
1) Go to Data Elements tab and find the main element name that your complex type is listed under.
2) Go to Types tab and find the type of the main element.
3) Expand it and find your own complex type. When you click on it, it will allow you to set Min Occurs, Max Occur and Looping Option here. Once you save your XML profile, the changes will get reflected in other tabs as well.
Example: Under Data Elements these fields are grayed out for your complex type:
In Types tab you can set those values:
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